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Article summary:
1. A unified strategy for the biomimetic total synthesis of the spiroindimicin family of natural products was reported.
2. Key transformations include a one-pot two-enzyme-catalyzed oxidative dimerization of L-tryptophan/5-chloro-L-tryptophan to afford the bis-indole precursors chromopyrrolic acid/5′,5′′-dichloro-chromopyrrolic acid.
3. Regioselective C3′−C2′′ and C3′−C4′′ bond formation converting a common bis-indole skeleton to two skeletally different natural products were also included in the synthesis.
Article analysis:
The article is written by a team of researchers from Peking University and National Yang Ming Chiao Tung University in China, and is published in Angewandte Chemie International Edition, which is a reputable journal with high standards for publication. The authors have provided detailed information about their research methods and results, as well as references to other relevant studies. The article does not appear to be biased or promotional in any way, and all potential risks are noted. Furthermore, both sides of the argument are presented equally, with no unsupported claims or missing points of consideration. In conclusion, this article appears to be reliable and trustworthy.